• 文献标题:   Detecting Mercury (II) and Thiocyanate Using "Turn-on" Fluorescence of Graphene Quantum Dots
  • 文献类型:   Article
  • 作  者:   ASKARI F, RAHDAR A, DASHTI M, TRANT JF
  • 作者关键词:   graphene quantum dot, hg2+, scn, fluorescent detection
  • 出版物名称:   JOURNAL OF FLUORESCENCE
  • ISSN:   1053-0509 EI 1573-4994
  • 通讯作者地址:   Univ Zabol
  • 被引频次:   0
  • DOI:   10.1007/s10895-020-02586-z EA JUL 2020
  • 出版年:   2020

▎ 摘  要

In this work, 1.8 nm graphene quantum dots (GQDs), exhibiting bright blue fluorescence, were prepared using a bottom-up synthesis from citric acid. The fluorescence of the GQDs could be almost completely quenched (about 96%) by adding Hg2+. Quenching was far less efficient with other similar heavy metals, Tl+, Pb2+ and Bi3+. Fluorescence could be near quantitatively restored through the introduction of thiocyanate. This "turn-on" fluorescence can thus be used to detect both or either environmental and physiological contaminants mercury and thiocyanate and could prove useful for the development of simple point-of-care diagnostics in the future.