• 文献标题:   Structure engineering of 3D interconnect graphene nanocapsules for microwave absorption
  • 文献类型:   Article
  • 作  者:   SHEN XY, RAN K, ZHENG BX, CHEN FZ
  • 作者关键词:   graphene nanocapsule, microwave absorption, carbon material, structure engineering
  • 出版物名称:   INORGANIC CHEMISTRY COMMUNICATIONS
  • ISSN:   1387-7003 EI 1879-0259
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.inoche.2023.110863 EA JUN 2023
  • 出版年:   2023

▎ 摘  要

Constructing porous structures is important for enhancing the impedance matching of carbon-based microwave absorbing materials (MAM) and achieving effective electromagnetic wave absorption. In this study, we prepared three-dimensional interconnected graphene nanocapsules (IGNCs) with a honeycomb-like structure using trisodium citrate dihydrate. During pyrolysis, sodium citrate dihydrate undergoes self-assembly and thermal polymerization, forming interconnected nanocapsules. The homogeneous distribution of Na2CO3 serves as a template for this process. The IGNCs-700 demonstrated an effective absorption bandwidth (EAB) of 4.32 GHz, at a fill concentration of only 5 wt% and a matched thickness of 2.3 mm. Finally, Computer Simulation Technology (CST) simulation results further validate the radar microwave absorption capability of the IGNCs-700 under farfield conditions.