• 文献标题:   Graphene oxide based nanohybrid proton exchange membranes for fuel cell applications: An overview
  • 文献类型:   Article
  • 作  者:   PANDEY RP, SHUKLA G, MANOHAR M, SHAHI VK
  • 作者关键词:   graphene oxide, nanohybrid proton exchange membrane, fuel cell, ionexchange membrane
  • 出版物名称:   ADVANCES IN COLLOID INTERFACE SCIENCE
  • ISSN:   0001-8686 EI 1873-3727
  • 通讯作者地址:   GSM Cent Salt Marine Chem Res Inst
  • 被引频次:   41
  • DOI:   10.1016/j.cis.2016.12.003
  • 出版年:   2017

▎ 摘  要

In the context of many applications, such as polymer composites, energy-related materials, sensors,'paper'-like materials, field-effect transistors (FET), and biomedical applications, chemically modified graphene was broadly studied during the last decade, due to its excellent electrical, mechanical, and thermal properties. The presence of reactive oxygen functional groups in the grapheme oxide (GO) responsible for chemical functionali2ation makes it a good candidate for diversified applications. The main objectives for developing a GO based nanohybrid proton exchange membrane (PEM) include: improved self-humidification (water retention ability), reduced fuel crossover (electro-osmotic drag), improved stabilities (mechanical, thermal, and chemical), enhanced proton conductivity, and processability for the preparation of membrane-electrode assembly. Research carried on this topic may be divided into protocols for covalent grafting of functional groups on GO matrix, preparation of free-standing PEM or choice of suitable polymer matrix, covalent or hydrogen bonding between GO and polymer matrix etc. Herein, we present a brief literature survey on GO based nano-hybrid PEM for fuel cell applications. Different protocols were adopted to produce functionalized GO based materials and prepare their free-standing film or disperse these materials in various polymer matrices with suitable interactions. This review article critically discussed the suitability of these PEMs for fuel cell applications in terms of the dependency of the intrinsic properties of nanohybrid PEMs. Potential applications of these nanohybrid PEMs, and current challenges are also provided along with future guidelines for developing GO based nanohybrid PEMs as promising materials for fuel cell applications. (C) 2016 Elsevier B.V. All rights reserved.