▎ 摘　　要

CdSe quantum dot sensitized solar cells (QDSCs) modified with graphene quantum dots (GQDs) have been successfully achieved in this work for the first time. Satisfactorily, the optimized photovoltage (V-oc) of the modified QDSCs was approximately 0.04 V higher than that of plain CdSe QDSCs, consequently improving the photovoltaic performance of the resulting QDSCs. Served as a novel coating on the CdSe QD sensitized photoanode, GQDs played a vital role in improving Vac due to the suppressed charge recombination which has been confirmed by electron impedance spectroscopy as well as transient photovoltage decay measurements. Moreover, different adsorption sequences, concentration and deposition time of GQDs have also been systematically investigated to boost the power conversion efficiency (PCE) of CdSe QDSCs. After the coating of CdSe with GQDs, the resulting champion CdSe QDSCs exhibited an improved PCE of 6.59% under AM 1.5G full one sun illumination. (C) 2015 Science Press and Dalian Institute of Chemical Physics. All rights reserved.