• 文献标题:   Transparent graphene oxide-Pt composite counter electrode fabricated by pulse current electrodeposition-for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   JANG HS, YUN JM, KIM DY, NA SI, KIM SS
  • 作者关键词:   dyesensitized solar cell, transparent, counter electrode, graphene oxidept composite, pulse current electrodeposition
  • 出版物名称:   SURFACE COATINGS TECHNOLOGY
  • ISSN:   0257-8972
  • 通讯作者地址:   Kunsan Natl Univ
  • 被引频次:   16
  • DOI:   10.1016/j.surfcoat.2013.12.075
  • 出版年:   2014

▎ 摘  要

To use as counter electrode in dye-sensitized solar cells (DSSCs) highly transparent graphene oxide (GO)-Pt composite film was fabricated via spin-coating of synthesized GO followed by pulse current (PC) electrodeposition of Pt, which has many benefits such as controlling of particle size and density, remarkable adhesion, uniform morphology, and simple and atmospheric pressure method without any use of vacuum systems. Compared to GO counter electrode, uniform distribution of Pt nanoparticles with a size of similar to 30 nm on GO leads to dramatic improvement of electrocatalytic activity toward the l(3)(-) + 2e(-) = 3I(-) reaction, and thus overall power conversion efficiency was increased from 3.99% to 7.10%. Moreover, GO-Pt composite counter electrode showed superior characteristics to PC electrodeposited Pt counter electrode showing ununiform distribution of Pt nanoparticles on rough fluorine-doped tin oxide (FTO) coated glass substrates. (C) 2014 Elsevier B.V. All rights reserved.