• 文献标题:   Pauli Repulsion-Induced Expansion and Electromechanical Properties of Graphene
  • 文献类型:   Article
  • 作  者:   WANG H, SHAN XN, CHEN HY, TAO NJ
  • 作者关键词:   pauli repulsion, graphene expansion, quantum capacitance, electromechanical properties of graphene, young s modulus of graphene
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   5
  • DOI:   10.1021/acs.nanolett.6b03955
  • 出版年:   2017

▎ 摘  要

Because graphene has nearly zero density of states at the Dirac point, charging it must overcome Pauli repulsion. We show here that this repulsion causes graphene to expand, which is measurable with an optical edge-tracking method despite that graphene is the strongest material. The expansion increases quadratically with applied voltage as predicted by theory and has a coefficient of similar to 10(-4) per Vat 1 V. Graphene has many attractive properties, but it lacks piezoelectricity, which limits its electromechanical applications. The observed Pauli repulsion-induced expansion provides an alternative way to electrically control graphene dimension. It also provides a simple and direct method to measure the elastic properties of graphene and other low dimensional materials.