• 文献标题:   Development of stripping voltammetry using glassy carbon electrode modified with electrochemical reduced graphene oxide for the determination of amaranth in soft drink and candy samples
  • 文献类型:   Article
  • 作  者:   NGUYEN TKT, LE THG, PHAM NTT, HOANG TH, NGUYEN H, NGUYEN MX, DANG MHG, DO HH, TA TT, BUI XT
  • 作者关键词:   amaranth, ergo, gce, adsorptive stripping voltammetry, cyclic voltammetry
  • 出版物名称:   MICROCHEMICAL JOURNAL
  • ISSN:   0026-265X EI 1095-9149
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.microc.2023.108467 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

In this study, the manufacturing conditions of glassy carbon electrode modified with electrochemical reduced graphene oxide (ErGO/GCE) were elucidated to determine amaranth in soft drink and candy samples by adsorptive stripping voltammatry. The ErGO/GCE was fabricated through an electrochemical reduction process of graphene oxide in the potential range from 0 V to-1.5 V using cyclic voltammetry method. Characteristics of graphene oxide and reduced graphene oxide were studied by FT-IR, XRD, TEM, SEM. Amaranth is adsorbed on the ErGO/GCE working electrode surface through an irreversible oxidation process. The optimal conditions used to determine amaranth are Britton-Robinson buffer solution of pH 3.0, an adsorption potential at 0 V, an adsorption time of 30 s, at a scan rate of 20 mV/s, a linearity range from 1.0 x 10-7 mol. L-1 to 1.0 x 10-6 mol. L-1, a (LOD) detection limit of 2.8 x 10-8 mol. L-1 and a (LOQ) qualification limit of 9.3 x 10-8 mol. L-1. The proposed method can be applied to determine amaranth dye in food.