• 文献标题:   Optical observation of different conformational isomers in rubrene ultra-thin molecular films on epitaxial graphene
  • 文献类型:   Article
  • 作  者:   UDHARDT C, FORKER R, GRUENEWALD M, WATANABE Y, YAMADA T, UEBA T, MUNAKATA T, FRITZ T
  • 作者关键词:   rubrene, organic molecular beam epitaxy, optical insitu spectroscopy, differential reflectance spectroscopy, low energy electron, diffraction, scanning tunneling microscopy, graphite
  • 出版物名称:   THIN SOLID FILMS
  • ISSN:   0040-6090
  • 通讯作者地址:   Univ Jena
  • 被引频次:   9
  • DOI:   10.1016/j.tsf.2015.12.023
  • 出版年:   2016

▎ 摘  要

Optical differential reflectance spectroscopy in combination with low-energy electron diffraction and scanning tunneling microscopy is used to investigate (ultra-) thin rubrene films grown on epitaxial graphene. The optical absorption behavior is compared to thin films on graphite(0001), muscovite mica(0001), and amorphous glass. All the optical spectra can be explained by the presence of two different spectral components, namely a high-energy and a low-energy component. We assign these two optical species to two different conformations of the rubrene molecule. (C) 2015 Elsevier B.V. All rights reserved.