▎ 摘　　要

We have realized the direct synthesis of ZnO nanorods (ZnO NRs) array on reduced graphene layer (rGO), and demonstrated the enhanced photoelectrochemical (PEC) property of the rGO/ZnO based photoanode under UV irradiation compared with the pristine ZnO NRs array. The introduction of the rGO layer resulted in a favorable energy band structure for electron migration, which finally led to the efficient photoinduced charge separation. Such nanostructure was subsequently employed for self-powered PEC biosensing of glutathione in the condition of 0 V bias, with a linear range from 10 to 200 mu M, a detection limit of 2.17 mu M, as well as excellent selectivity, reproducibility and stability. The results indicated the rGO/ZnO nanostructure is a competitive candidate in the PEC biosensing field. (C) 2014 Elsevier B.V. All rights reserved.