• 文献标题:   Oxygen Reduction and Evolution in an Ionic Liquid Electrocatalyzed by a Highly Active Au Nanoparticles/Graphene Hybrid
  • 文献类型:   Article
  • 作  者:   QIU XY, ZHOU W, QI CZ, CHENG DH, OUCHI Y
  • 作者关键词:   au nanoparticle, graphene nanosheet, ionic liquid, metalair batterie, oxygen reduction reaction
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   2
  • DOI:   10.1002/celc.201600876
  • 出版年:   2017

▎ 摘  要

A hybrid of reduced graphene oxide (RGO) sheets and gold nanoparticles (AuNPs), which mainly feature Au(111) planes and have an average diameter of 8 nm, has been prepared by using a facile approach. The RGO/AuNPs hybrid exhibits high bifunctional electrocatalytic activity toward the oxygen reduction reaction (ORR) as well as the oxygen evolution reaction (OER) in room-temperature ionic liquid (RTIL). Compared with the performance of a commercial Pt/C material, a higher ORR current density as well as a much better reversibility of ORR/OER has been obtained on RGO/AuNPs, suggesting that this novel hybrid material could be employed as a promising catalyst for the development of IL-based rechargeable metal-air batteries.