• 文献标题:   Electrical conduction mechanisms in graphene nanoplatelet/yttria tetragonal zirconia composites
  • 文献类型:   Article
  • 作  者:   POYATO R, OSUNA J, MORALESRODRIGUEZ A, GALLARDOLOPEZ A
  • 作者关键词:   graphene nanoplatelet, 3ytzp, ceramic composite, electrical, conductivity, conduction mechanism
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Univ Seville
  • 被引频次:   5
  • DOI:   10.1016/j.ceramint.2018.05.082
  • 出版年:   2018

▎ 摘  要

Yttria tetragonal zirconia polycrystalline (3YTZP) ceramic composites with 5, 10 and 20 vol% graphene nano-platelets (GNPs) were prepared by spark plasma sintering (SPS) and their electrical conductivity as a function of temperature was characterized. The composites exhibit anisotropic microstructures so the electrical conductivity studies were carried out in two directions: perpendicular (sigma(perpendicular to)) and parallel (sigma(parallel to)) to the SPS pressing axis. The composites with 5 and 10 GNP vol% showed high electrical anisotropy, whereas the composite with 20 GNP vol % exhibited nearly isotropic electrical behavior. sigma(perpendicular to) shows metallic-type behavior in the composites with 10 and 20 vol% GNP revealing that charge transport takes place through defect-free GNPs. For the composite with 5 vol % GNP the observed semiconductor-type behavior was explained by a two dimensional variable range hopping mechanism. sigma(parallel to)shows metallic-type conductivity in the composite with 20 GNP vol% and positive d sigma(parallel to)/dT slope in the composites with 5 and 10 GNP vol%.