• 文献标题:   Hydrothermal preparation of nitrogen-doped graphene sheets via hexamethylenetetramine for application as supercapacitor electrodes
  • 文献类型:   Article
  • 作  者:   LEE JW, KO JM, KIM JD
  • 作者关键词:   nitrogendoped graphene, hexamethylenetetramine, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   114
  • DOI:   10.1016/j.electacta.2012.08.070
  • 出版年:   2012

▎ 摘  要

Nitrogen-doped graphene sheets (NGS) were obtained using a simple hydrothermal reaction with graphene oxide and hexamethylenetetramine (HMT). HMT plays important roles in both reducing graphene oxide and doping nitrogen into the graphene sheets. The prepared nitrogen-doped graphene sheets reduced by hexamethylenetetramine (NGS-HMT) have a high nitrogen (8.62 atom%) content, in which various nitrogen species, such as pyridinic-N, pyrrolic-N, and quaternary-N, are detected. For supercapacitor applications, NGS-HMT shows a value of 161 Fg(-1) at a current density of 0.5 Ag-1, and it also exhibits a high cycle stability. (C) 2012 Elsevier Ltd. All rights reserved.