• 文献标题:   Annealing induced electrical conduction and band gap variation in thermally reduced graphene oxide films with different sp(2)/sp(3) fraction
  • 文献类型:   Article
  • 作  者:   SINGH M, YADAV A, KUMAR S, AGARWAL P
  • 作者关键词:   thermally reduced go, temperature dependent electrical, conductivity, activation energy, sp 2 /sp 3 fraction, band gap
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Indian Inst Technol
  • 被引频次:   23
  • DOI:   10.1016/j.apsusc.2014.11.121
  • 出版年:   2015

▎ 摘  要

Temperature dependent electrical conductivity of as prepared and thermally reduced graphene oxide (GO) thin films was measured in the range 300-520 K. As prepared GO films show very low conductivity similar to 6.8 x 10(-6) S/cm at 300 K, which increases slowly till 370K. A sharp increase in conductivity is observed in the temperature range 370-440 K, beyond which conductivity is thermally activated with activation energy 0.26 eV. Reduced GO films show an increase in conductivity at 300 K with increase in reduction temperature. GO films reduced at 400 C exhibit high conductivity similar to 40 S/cm at 300 K, with very low activation energy 0.05 eV in the measured temperature range 300-520 K. The increase in conductivity after thermal reduction is due to an increase in the ratio sp(2)/sp(3) bonded carbon atoms. The band gap of as prepared GO is 3.20 eV and it is decreased by approximately 0.4 eV in the case of thermally reduced GO at 400 degrees C in comparison to as prepared GO. (C) 2014 Elsevier B.V. All rights reserved.