• 文献标题:   A novel CuS/graphene-coated separator for suppressing the shuttle effect of lithium/sulfur batteries
  • 文献类型:   Article
  • 作  者:   LI HP, SUN LC, ZHAO Y, TAN TZ, ZHANG YG
  • 作者关键词:   lithiumsulfur batterie, polysulfide immobilization, multifunctional separator, cus, graphene
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Hebei Univ Technol
  • 被引频次:   21
  • DOI:   10.1016/j.apsusc.2018.10.046
  • 出版年:   2019

▎ 摘  要

Herein, we demonstrate a facile synthesis process to fabricate and deposit flower-like CuS/graphene nano- composite on a multi-functional separator for efficient immobilization of polysulfides of lithium/sulfur (Li/S) batteries. Admirably, as-prepared CuS/graphene composite endows enriched oxygen-functional groups and excellent electrical conductivity for cathode area. The introduction of CuS/graphene-coated separator effectively reduced the dissolution of lithium polysulfides as well as enhanced the integrity of the sulfur cathode for Li/S batteries. The cell with these modified separator delivered an enviable discharge capacity of 1302 mAh g(-1) at 0.2 C, as well as an excellent reversible capacity of 760 mAh g(-1) after 100 cycles. Furthermore, an outstanding rate capability of 568 mAh g(-1 )at 3.0 C has been achieved in the cell with CuS/graphene-coated separator. The results reveal that CuS/graphene-coated separator shows an admirable potentiality to boost the performance of next-generation Li/S batteries.