• 文献标题:   Emerging Bottom-Up Strategies for the Synthesis of Graphene Nanoribbons and Related Structures
  • 文献类型:   Review
  • 作  者:   JOLLY A, MIAO DD, DAIGLE M, MORIN JF
  • 作者关键词:   aromatization, carbon material, graphene nanoribbon, nanographene, polycyclic aromatic hydrocarbon
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Univ Laval
  • 被引频次:   8
  • DOI:   10.1002/anie.201906379 EA DEC 2019
  • 出版年:   2020

▎ 摘  要

The solution-phase synthesis is one of the most promising strategies for the preparation of well-defined graphene nanoribbons (GNRs) in large scale. To prepare high quality, defect-free GNRs, cycloaromatization reactions need to be very efficient, proceed without side reaction and mild enough to accommodate the presence of various functional groups. In this Minireview, we present the latest synthetic approaches for the synthesis of GNRs and related structures, including alkyne benzannulation, photochemical cyclodehydrohalogenation, Mallory and Pd- and Ni-catalyzed reactions.