• 文献标题:   Electrochemical Method for Analysis of Cholesterol Based on In Situ Synthesized Graphene Decorated with Zinc Oxide Nanoparticles
  • 文献类型:   Article
  • 作  者:   WATANABE E, SPIDLE R, CAUDLE S, MANANI G, WANEKAYA AK, MUGWERU A
  • 作者关键词:  
  • 出版物名称:   ECS SOLID STATE LETTERS
  • ISSN:   2162-8742
  • 通讯作者地址:   Rowan Univ
  • 被引频次:   8
  • DOI:   10.1149/2.001401ssl
  • 出版年:   2014

▎ 摘  要

Graphene decorated with zinc oxide nanoparticles were synthesized in a single step. Through this process zinc oxide nanoparticles were deposited onto graphene nanosheets. The nano-composites were characterized using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), energy dispersive spectroscopy (EDX), cyclic voltammetry and electrochemical impedance spectroscopy. The nanocomposite material displayed excellent catalytic properties toward Cholesterol in combination with cholesterol oxidase (ChOx). The cholesterol detection limit was found to be 5.0 mu mol L-1 and a sensitivity 1.3 mu A/mu M cm(2) with linear correlation coefficient R-2 = 0.980. The Cholesterol oxidation also followed the Michaelis-Menten kinetics with apparent Km of 46.5 mu M (C) 2013 The Electrochemical Society. All rights reserved.