• 文献标题:   Preparation of bottom-up graphene oxide using citric acid and tannic acid, and its application as a filler for polypropylene nanocomposites
  • 文献类型:   Article
  • 作  者:   SHIN H, LIM MY, OH J, LEE Y, LEE JC
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1039/d0ra09856f
  • 出版年:   2021

▎ 摘  要

The production of graphene oxide (GO) in large amounts for commercialization in the chemical industry has been limited because harsh and tedious process conditions are required. In this study, a novel carbon nanomaterial called 'bottom-up graphene oxide (BGO)' could be easily prepared for the first time by heat treatment of the mixture of citric acid (CA) and tannic acid (TA) with different weight ratios for the first time. BGO3 prepared using a 50/50 weight ratio of CA/TA was found to have an average lateral size of 250.0 nm and an average thickness of 7.2 nm, and it was further functionalized with cardanol to prepare cardanol functionalized BGO3 (CBGO3) to be used as a filler for the polypropylene (PP) nanocomposite, where cardanol was used to increase the compatibility between BGO3 and PP. The improved mechanical properties and thermal stability of PP nanocomposites containing CBGO3 could be ascribed to the intrinsic mechanical properties of the carbon nanomaterial and the increased compatibility by the attached cardanol on BGO3.