• 文献标题:   Ceramic supported attapulgite-graphene oxide composite membrane for efficient removal of heavy metal contamination
  • 文献类型:   Article
  • 作  者:   LI W, WANG DJ, SOOMRO RA, FU F, QIAO N, YU Y, WANG R, XU B
  • 作者关键词:   graphene oxide, ceramic, nanofiltration, attapulgite, heavy metal contamination
  • 出版物名称:   JOURNAL OF MEMBRANE SCIENCE
  • ISSN:   0376-7388 EI 1873-3123
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   4
  • DOI:   10.1016/j.memsci.2019.117323
  • 出版年:   2019

▎ 摘  要

Ceramic supported graphene oxide (GO)/Attapulgite (ATP) composite membrane (GOA) was simply prepared by vacuum filtration for efficient removal of heavy metal contamination. The ATP nanorods were incorporated within the laminar layers of GO, influencing the interlayer distance and facilitating greater number of channels for enhanced water transportation. The GOA possessed greater surface wettability with improved water flux rate of 6.3 L m(-2) h(-1) compared to 0.4 L m(-2) h(-1) measured for its pristine counter-part. The GOA demonstrated excellent rejection efficiency (nearly 100%) for heavy metal ions such as Cu2+, Ni2+, Pb2+ and Cd2+. The excellent separation efficiency of GOA could be ascribed to the synergic combination of size exclusion effect based on the formation of 3D network structures between the GO layers and increased electrostatic interaction in between the negatively charged surface moieties of GOA and heavy metal ions. More importantly, the use of Al2O3 as a support substrate resulted in improved stability and allowed extended usage of the membrane for a period of 3500 min while maintaining 99% rejection efficiency for Cu2+ ions. The high flux rate, great water stability and prominent rejection capability of the designed membrane is suggestive of its practical application in removal of heavy metal contamination from water.