• 文献标题:   Gold-functionalized graphene as conductive filler in UV-curable epoxy resin
  • 文献类型:   Article
  • 作  者:   MARTINGALLEGO M, LOPEZMANCHADO MA, CALZA P, ROPPOLO I, SANGERMANO M
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Politecn Torino
  • 被引频次:   11
  • DOI:   10.1007/s10853-014-8619-z
  • 出版年:   2015

▎ 摘  要

Graphene sheets (GNPs) were functionalized with gold nanoparticles via a spontaneous deposition of gold particles on its surface occurred by chemical reduction of (Au3+). Even after only 1 min of reaction, the reduction of Au3+ into metallic Au-0, takes place in evidencing the rapid and spontaneous character of the reduction. The particles, after only 3 min of deposition, have very small diameters, with average centred at 17 nm. The Au-GNP nanofillers were dispersed into UV-curable epoxy resin. Conductivity of the epoxy crosslinked samples containing Au-GNP nanofiller were compared to the values obtained for epoxy nanocomposite containing the same amount of bare graphene; the electrical conductivity was significantly increased by the addition of Au-GNP nanofiller, of about four orders of magnitude. This could be attributed to a charge transfer mechanism, which is strongly enhanced by the presence of gold NPs.