• 文献标题:   Electrochemical synthesis of a graphene sheet and gold nanoparticle-based nanocomposite, and its application to amperometric sensing of dopamine
  • 文献类型:   Article
  • 作  者:   LI SJ, DENG DH, SHI Q, LIU SR
  • 作者关键词:   graphene, nanocomposite, dopamine, electrochemical sensor
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Anyang Normal Univ
  • 被引频次:   73
  • DOI:   10.1007/s00604-012-0782-9
  • 出版年:   2012

▎ 摘  要

We describe a simple, green and controllable approach for electrochemical synthesis of a nanocomposite made up from electrochemically reduced graphene oxide (ERGO) and gold nanoparticles. This material possesses the specific features of both gold nanoparticles and graphene. Its morphology was characterized by scanning electron microscopy which reveals a homogeneous distribution of gold nanoparticles on the graphene sheets. Cyclic voltammetry was used to evaluate the electrochemical properties of this nanocomposite towards dopamine by modification of it on surface of glassy carbon electrode (GCE). Compared to the bare GCE, the electrode modified with gold nanoparticles, and the electrode modified with ERGO, the one modified with the nanocomposite displays better electrocatalytic activity. Its oxidation peak current is linearly proportional to the concentration of dopamine (DA) in the range from 0.1 to 10 mu M, with a detection limit of 0.04 mu M (at S/N = 3). The modified electrode also displays good storage stability, reproducibility, and selectivity.