• 文献标题:   Flexible micro-supercapacitor based on in-situ assembled graphene on metal template at room temperature
  • 文献类型:   Article
  • 作  者:   WU ZK, LIN ZY, LI LY, SONG B, MOON KS, BAI SL, WONG CP
  • 作者关键词:   microstipercapacitor, graphene, flexible, selfassemble, roomtemperature
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855 EI 2211-3282
  • 通讯作者地址:   Peking Univ
  • 被引频次:   77
  • DOI:   10.1016/j.nanoen.2014.09.019
  • 出版年:   2014

▎ 摘  要

Graphene based micro-supercapacitors (MSCs) have been extensively studied in recent years; however, few of them report room temperature fabricating methods for flexible MSC. Here we developed a convenient procedure based on simultaneous self-assembly and reduction of graphene oxide (GO) on Cu/Au interdigit at room temperature. The as-produced MSC shows a specific areal capacitance of 0.95 mF cm(-2) and maintains 98.3% after 11,000 cycles of charge and discharge. Extremely small relaxation time constants of 1.9 ms in aqueous electrolyte and 4.8 ms in gelled electrolyte are achieved. Also the device shows great flexibility and retains 93.5% of the capacitance after 5000 times of bending and twisting tests. (C) 2014 Elsevier Ltd. All rights reserved.