• 文献标题:   Synergistic effect of beta-Bi2O3 and graphene/MWCNT in silicone-based polymeric matrices on diagnostic X-ray attenuation
  • 文献类型:   Article
  • 作  者:   JAYAKUMAR S, SARAVANAN T, VADIVEL M, PHILIP J
  • 作者关键词:   xray attenuation, bi2o3, graphene, mwcnt, nanocomposite, nanofiller
  • 出版物名称:   APPLIED NANOSCIENCE
  • ISSN:   2190-5509 EI 2190-5517
  • 通讯作者地址:   Indira Gandhi Ctr Atom Res
  • 被引频次:   1
  • DOI:   10.1007/s13204-019-00972-z
  • 出版年:   2019

▎ 摘  要

The prolonged exposure of high-energy ionizing radiations during treatment of cancer/tumour and radiological examinations is hazardous to occupational workers and patients. Lead-incorporated composite materials are traditionally used as radiopaque fabrics, but are heavy, bulky and hence often cause inconvenience to users. Therefore, superior radiopaque protective wears that are preferably lead-free, light weight and flexible are being explored. Towards this goal, we study here the synergistic effect of graphene nanoplatelets and multi-walled carbon nanotube (MWCNT) on the X-ray attenuation property of polymer nanocomposites containing beta-Bi2O3 nanofillers. The effect of graphene and MWCNT at different concentrations on Bi2O3-based polymer nanocomposites is studied to attain optimal compositions with respect to its X-ray attenuation property and thermal stability. Surface topography and surface roughness of the nanocomposite blocks are studied using an atomic force microscope (AFM). The effect of the density of polymer on the curing, thermal stability and X-ray attenuation property is also studied by using silicone polymers of density 1.7 (G1) and 1.04 g/cm(3) (G2). The X-ray attenuation property of nanocomposites with G1 polymer matrix is found to be better than that of G2. The G1-based nanocomposite containing beta-Bi2O3 and graphene is found to be better than the one with G1 polymer containing beta-Bi2O3 and MWCNT. Thermal stability of multifiller nanocomposites is found to be better than the one without nanofillers. AFM topography images show a variation in surface roughness of nanocomposites with different fillers, which contributes to the different micro- and nano-structural architectures due to polymer-nanofiller interaction, thereby, affecting the X-ray attenuation of the nanocomposites. Our study shows that the multifiller nanocomposite containing beta-Bi2O3 and graphene nanoplatelets offer greater potential for the development of efficient radiopaque fabric materials.