• 文献标题:   Ultra-stable phosphor of h-BN white graphene-loaded all-inorganic perovskite nanocrystals for white LEDs
  • 文献类型:   Article
  • 作  者:   WU ZH, WANG P, WU J, WEI J, SUN YN, WANG NP, ZHAO ZF
  • 作者关键词:   ultrastable, perovskite nanocrystal, boron nitride white graphene, whiteled
  • 出版物名称:   JOURNAL OF LUMINESCENCE
  • ISSN:   0022-2313 EI 1872-7883
  • 通讯作者地址:   818 Fenghua Rd
  • 被引频次:   3
  • DOI:   10.1016/j.jlumin.2019.116941
  • 出版年:   2020

▎ 摘  要

Recently, all-inorganic perovskite (CsPbX3 (X = Cl, Br, I)) nanocrystals (NCs) have caused extensive attention due to their high photoluminescence quantum yield (PL QY), high color purity, and narrow full width at half maximum (FWHM). Although the excellent optical properties of perovskite NCs (PNCs) endow them good application prospects, their inherent instability severely limits the commercialization process. In this paper, highly-luminescence and ultra-stable phosphor were obtained by loading PNCs onto the surface of amino modified hexagonal boron-nitride (h-BN) white graphene (PNCs-BNWG), This structural design can effectively suppress the attenuation of photoluminescence (PL) intensity and enhance thermal stability, thereby realizing the high stability and brightness white LEDs. The synthesis process is simple and can be finished in a few minutes to ensure scalable production. Compared with bare PNCs, it can maintain excellent optical properties. The high PL QY and thermal stability mainly stem from the isolation effect that separates PNCs from each other on the surface of BNWG and their superior high transparency as well as thermal conductivity. In addition, multi-color inks are produced by dispersing PNCs-BNWG nanocomposites in PDMS to form a multicolor painting demonstrating high PL QY and wide color gamut.