• 文献标题:   High performance concentration capacitors with graphene hydrogel electrodes for harvesting salinity gradient energy
  • 文献类型:   Article
  • 作  者:   ZHAN F, WANG ZJ, WU TT, DONG Q, ZHAO CT, WANG G, QIU JS
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Dalian Univ Technol
  • 被引频次:   5
  • DOI:   10.1039/c7ta11070g
  • 出版年:   2018

▎ 摘  要

Salinity gradient energy (SGE) is the energy available from the salinity difference between freshwater and saltwater. Herein, we propose a concentration capacitor as a novel capacitive mixing (CapMix) technique to harvest SGE. The concentration capacitor comprises identical electrodes and a membrane that separates concentrated and diluted solutions that alternately flow through the capacitor. Graphene hydrogel (GH) electrodes and a filtration membrane (FM) or an anion exchange membrane (AEM) are used to construct GH//FM//GH and GH//AEM//GH concentration capacitors. These concentration capacitors show excellent performance in harvesting SGE, particularly the GH//AEM//GH concentration capacitor, whose voltage rise and average power density can reach 288.5 mV and 482.4 mW m(-2), respectively, which are higher than those obtained with other CapMix techniques. The outstanding performance is associated with the double-channel construction, the membrane potential, and the macroporous structure and abundant negative charge of the GH electrodes. Our results show that the concentration capacitor is a promising approach for efficiently extracting SGE.