• 文献标题:   Tailored manganese hexacyanoferrate/graphene oxide nanocomposites: one-pot facile synthesis and favorable capacitance behavior for supercapacitors
  • 文献类型:   Article
  • 作  者:   YANG TT, GAO J, ZHOU LH, HE QH, CHEN SX, HE P, JIA B, LEI H, DONG FQ, ZHANG H
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Southwest Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.1007/s10854-019-02812-w
  • 出版年:   2020

▎ 摘  要

Prussian blue analogues have been widely investigated in the field of materials chemistry because of its low cost, high porosity, and excellent redox reversibility. Herein, a series of MnHCF/GO nanocomposites (MHG) with diverse GO contents have been successfully prepared at room temperature through a facile and cost-effective chemical precipitation method. It is indicated that MnHCF nanoparticles anchor on the surface of GO nanosheets, forming a well-coupled hybrid nanostructure. GO nanosheets can not only ameliorate the agglomeration of MnHCF nanoparticles, but also boost the electron/ion transport in the electrolyte. In addition, the synergistic effect between MnHCF nanoparticles and GO nanosheets can improve the electrochemical properties of MHG nanocomposites. MHG-3-based electrode with 20 wt% GO nanosheets exhibits a specific capacitance of 279.3 F g(-1), which is approximately three times higher than that of pristine MnHCF electrode at 0.3 A g(-1). Moreover, MHG-3-based electrode exhibits favorable cyclic stability (65.3% after 2000 continuous charge/discharge cycles at 0.8 A g(-1)).