• 文献标题:   Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices
  • 文献类型:   Article
  • 作  者:   SHEN JM, HAN K, MARTIN EJ, WU YY, KUNG MC, HAYNER CM, SHULL KR, KUNG HH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Northwestern Univ
  • 被引频次:   20
  • DOI:   10.1039/c4ta04852k
  • 出版年:   2014

▎ 摘  要

A thermally responsive membrane separator, suitable for use in nonaqueous electrolytes, was constructed by grafting a UCST polymer, poly(sulfobetaine), onto graphene oxide sheets. When heated from 20 to 80 degrees C, it decreased the specific storage capacity of the electrode for Li by >50% reversibly, compared to 30% increase without polymer modification.