• 文献标题:   Exploring the structure and chemical activity of 2-D gold islands on graphene moire/Ru(0001)
  • 文献类型:   Article
  • 作  者:   XU Y, SEMIDEYFLECHA L, LIU L, ZHOU ZH, GOODMAN DW
  • 作者关键词:  
  • 出版物名称:   FARADAY DISCUSSIONS
  • ISSN:   1359-6640 EI 1364-5498
  • 通讯作者地址:   Oak Ridge Natl Lab
  • 被引频次:   32
  • DOI:   10.1039/c1fd00030f
  • 出版年:   2011

▎ 摘  要

Au deposited on Ru(0001)-supported extended, continuous graphene moire forms large 2-D islands at room temperature that are several nanometers in diameter but only 0.55 nm in height, in the apparent absence of typical binding sites such as defects and adsorbates. These Au islands conform to the corrugation of the underlying graphene and display commensurate moire patterns. Several extended Au structure models on graphene/Ru(0001) are examined using density functional theory calculations. Close-packed Au overlayers are energetically more stable, but all interact weakly with the support. Preliminary tests found the Au islands/graphene/Ru(0001) surface to be active for CO oxidation at cryogenic temperature, which suggests that the Au itself is the locus of catalytic activity.