• 文献标题:   Performance Study of Graphene Oxide as an Antierosion Coating for Ornamental and Heritage Dolostone
  • 文献类型:   Article, Early Access
  • 作  者:   MARTINEZGARCIA R, GONZALEZCAMPELO D, FRAILEFERNANDEZ FJ, CASTANON AM, CALDEVILLA P, GIGANTO S, ORTIZMARQUES A, ZELLI F, CALVO V, GONZALEZDOMINGUEZ JM, FERNANDEZRAGA M
  • 作者关键词:   coating, dolostone, durability, erosion, graphene oxide, heritage, limestone
  • 出版物名称:   ADVANCED MATERIALS TECHNOLOGIES
  • ISSN:   2365-709X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/admt.202300486 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

Concern for the perpetuation of stone monuments is deeply ingrained in humans; however, despite the attempts made in this field, there is still a great deal of effort needed to bring about advancements in the conservation of ornamental stone. Erosive agents, such as rain, extreme temperatures, and chemical and biological agents, threaten our stone heritage and gradually wear away buildings, sculptures, and other monuments found all around the world. Limestone and dolostone have been widely used throughout history, given their ease of extraction and workability. Nevertheless, these properties make them particularly vulnerable to the aforementioned erosive agents, for which the main solution at present is costly and time-consuming restoration. Given the scarcity of effective and durable agents to prevent the deterioration of ornamental and heritage stones, and as graphene oxide (GO) has recently shown impressive effectiveness for this task, this work will further explore the viability of GO as a protective coating for monumental dolostone. For this purpose, GO is sprayed over dolostone surfaces by water dispersion with no adjuvants. The coating performance is assessed in terms of thermal stress, optical inspection (structured light 3D scanner), colorimetry, leachate analysis, and electron microscopy. The main results show that spray-coated GO over stone surfaces creates a highly protective and durable barrier without altering their aesthetic qualities.