▎ 摘　　要

Electrocatalytic reduction of CO2 with non-precious materials containing the Co-N-C moiety as a catalyst is considered to be a promising method to achieve carbon neutrality. Unfortunately, metal phthalocyanines with an intrinsic Co-pyrrolic N-4-C structure usually show low electrocatalytic activity due to serious aggregation and low conductivity. Here, we exhibit a simple strategy to controllably disperse cobalt phthalocyanine (CoPc) on graphene oxide (GO) by the hydrolysis of protonated CoPc in GO aqueous phase. CoPc/GO nanocomposites with different ratios and structures could be easily obtained, and their effect on the electrocatalytic activity for the CO2 reduction reaction (CO2RR) to CO was systematically investigated. In the optimal sample, a CO selectivity of >96% can be achieved with an overpotential of <190 mV. Meanwhile, a CO Faradaic efficiency (FECO) of >90% can be reached within a wide potential range from -0.7 to -1.0 V (vs. RHE). The systematical experiments reveal that the synergy of CoPc and GO should be crucial owing to the existence of strong electrostatic interactions at the initial stage of hydrolysis and subsequent pi-pi, hydrogen bond and axial coordination interactions between CoPc and GO. This work exhibits a simple strategy to prepare molecule-based nanostructures as highly efficient electrocatalysts.