• 文献标题:   Determination of Rutin by a Graphene-Modified Glassy Carbon Electrode
  • 文献类型:   Article
  • 作  者:   LEI Y, DU DX, TANG LN, TAN CK, CHEN KL, ZHANG GJ
  • 作者关键词:   rutin, electrochemistry, graphene, cyclic voltammetry, differential pulse voltammetry
  • 出版物名称:   ANALYTICAL LETTERS
  • ISSN:   0003-2719 EI 1532-236X
  • 通讯作者地址:   Hubei Univ Chinese Med
  • 被引频次:   14
  • DOI:   10.1080/00032719.2014.966376
  • 出版年:   2015

▎ 摘  要

A reduced graphene oxide-modified glassy carbon electrode for sensitive detection of rutin is reported. The modified electrode was obtained by one-step electrochemical reduction of graphene oxide on the bare glassy carbon electrode. In the presence of graphene, an enhanced electrochemical response for rutin appeared with a pair of well-defined anodic and cathodic peaks in pH 3.0 phosphate buffer. Under the optimized conditions, the anodic peak currents exhibited a linear relationship with rutin concentration from 0.1 to 2.0 mu M with a detection limit of 23.2nM. The modified electrode was employed to the analysis of tablets (with satisfactory recovery of 19.96mg/per tablet) and Flos Sophorae. The graphene-modified electrode exhibited high sensitivity, good stability, and selectivity for the determination of rutin.