• 文献标题:   A Fe/Fe3O4/N-carbon composite with hierarchical porous structure and in situ formed N-doped graphene-like layers for high-performance lithium ion batteries
  • 文献类型:   Article
  • 作  者:   LI Y, MENG Q, ZHU SM, SUN ZH, YANG H, CHEN ZX, ZHU CL, GUO ZP, ZHANG D
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   22
  • DOI:   10.1039/c4dt03615h
  • 出版年:   2015

▎ 摘  要

Fe/Fe3O4/N-carbon composite consisting of a porous carbon matrix containing a highly conductive N-doped graphene-like network and Fe/Fe3O4 nanoparticles was prepared. The porous carbon has a hierarchical structure which is inherited from rice husk and the N-doped graphene-like network formed in situ. When used as an anode material for lithium batteries, the composite delivered a reversible capacity of approximately 610 mA h g(-1) at a current density of 200 mA g(-1) even after 100 cycles, due to the synergism between the unique hierarchical porous structures, highly electrically conductive N-doped graphene- like networks and nanosized particles of Fe/Fe3O4. This work provides a simple approach to prepare N-doped porous carbon activated nanoparticle composites which could be used to improve the electrochemical performance of lithium ion batteries.