• 文献标题:   Flash foam stamp-inspired fabrication of flexible in-plane graphene integrated micro-supercapacitors on paper
  • 文献类型:   Article
  • 作  者:   ZHAO J, SHI QL, GUO YY, WANG XF, WANG DB, TAN FR, JIANG L, YU Y
  • 作者关键词:   flexible, microsupercapacitor, electrochemically exfoliated graphene, flash foam stamp, paperbased, inplane
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Nanjing Univ Posts Telecommun
  • 被引频次:   5
  • DOI:   10.1016/j.jpowsour.2019.226703
  • 出版年:   2019

▎ 摘  要

Developing patterning techniques with practicability, cost-effectiveness and safety are essential for shape confirmable integrated energy storage devices. Herein we design a novel flash foam stamp-inspired technique for simple fabrication of flexible high energy in-plane micro-supercapacitors based on interdigital electrodes of self-depositing electrochemically exfoliated graphene on paper substrates. This technique is an attractive and novel bottom-up microfabrication technology due to its advantages of simplicity and low-cost. These novelly developed all-solid-state, paper-based in-plane graphene micro-supercapacitors exhibit excellent electrochemical performances, such as high area specific capacitance of 4.02 mF cm(-2) and excellent cycling stability (95.6% retention at 0.08 mA cm(-2) for 5000 cycles). And these solid-state flexible micro-supercapacitors are observed non-obvious structural change and loss of performance under bending state, suggesting remarkable flexibility and mechanical stability. Therefore, such all-solid-state, flexible paper-based graphene micro-supercapacitors can potentially be used for wearable and portable electronics.