• 文献标题:   Heteroatom-Doped Carbon Nanotube and Graphene-Based Electrocatalysts for Oxygen Reduction Reaction
  • 文献类型:   Review
  • 作  者:   LI JC, HOU PX, LIU C
  • 作者关键词:   carbon nanotube, graphene, heteroatom doping, oxygen reduction
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   50
  • DOI:   10.1002/smll.201702002
  • 出版年:   2017

▎ 摘  要

Oxygen reduction reaction (ORR) is a key step that determines the performance of a variety of energy storage and conversion devices, such as fuel cells and metal-air batteries. Heteroatom-doped carbon nanotubes (CNTs) and graphenes have attracted increasing interest and hold great promise as efficient ORR catalysts to replace noble-metal-based catalysts, owing to their unique structure characteristics, excellent physicochemical properties, low cost, and rich resources. In this review, recent progress on the design, fabrication, and performance of heteroatom-doped CNT- and graphene-based catalysts is summarized, aiming to provide insights into the working mechanism of these heteroatom-doped nanocarbons in ORR. The advantages, challenges that remain, and possible solutions of these nanocarbon-based electrocatalysts are discussed. Finally, future developing trends of the CNT and graphene-based ORR catalysts are proposed.