• 文献标题:   Three-dimensional graphene anchored Fe2O3@C core-shell nanoparticles as supercapacitor electrodes
  • 文献类型:   Article
  • 作  者:   ZHANG M, SHA JW, MIAO XY, LIU EZ, SHI CS, LI JJ, HE CN, LI QF, ZHAO NQ
  • 作者关键词:   supercapacitor, reduced graphene oxide, coreshell nanoparticle, network, carboncoated, fe2o3 nanoparticle cluster
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   21
  • DOI:   10.1016/j.jallcom.2016.12.058
  • 出版年:   2017

▎ 摘  要

Three-dimensional (3D) reduced graphene oxide (rGO) anchored carbon-coated Fe2O3 core-shell nano-particles (Fe2O3@C-rGO) has been developed successfully through a simple one-pot hydrothermal process followed by a further annealing treatment. The 3D Fe2O3@C-rGO nanocomposite consists of carbon-coated Fe2O3 nanoparticle clusters (Fe2O3@C) and rGO nanosheets. The homogenously distributed and intercalated Fe2O3@C nanoparticles between rGO nanosheets form a highly conductive 3D carbon network with rGO, and present a hierarchical pore size structure, enabling fast ion and electron transport, as well as remarkable specific surface area. The electrochemical performance in supercapacitor has been characterized, and the as-prepared Fe2O3@C-rGO electrode shows a significant high specific capacitance of 211.4 F/g at 0.5 A/g and 177.2 F/g at 20 A/g with no visible performance decay even after 2500 cycles testing. These properties indicate a good potential to achieve high performance electrochemical devices. (C) 2016 Elsevier B.V. All rights reserved.