• 文献标题:   Fabrication of high-rate microsupercapacitors by ultraviolet laser-assisted scribing of fluorinated graphene films
  • 文献类型:   Article
  • 作  者:   SYSOEV VI, GORODETSKIY DV, POPOV KM, MAKAROVA AA, BULUSHEVA LG, OKOTRUB AV
  • 作者关键词:   microsupercapactior, laser patterning, graphene, fluorination, impedance spectroscopy, energy storage
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jpowsour.2022.232549 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

The work presents the scalable fabrication of microsupercapacitors by scribing fluorinated graphene (FG) films using a low-power ultraviolet (UV) laser. The interaction of the FG film with UV light leads to its transformation to a few-layer graphene-like material with a tunable composition and structure. In the resulting graphene/FG hybrids, the patterned graphene sections act as electrodes, while the dielectric FG areas serve as a separator/ electrolyte storage. The electrochemical characteristics of the samples were studied by cyclic voltammetry, galvanostatic charge-discharge measurements and impedance spectroscopy. The best microsupercapacitors have an areal capacitance of 0.35 mF cm-2 at 0.02 V s- 1, a power density of 5580 mu W cm-2, and a capacity retention of 84% over the scan rate range of 0.01-1 V s- 1.