• 文献标题:   A glucose biosensor based on direct electrochemistry of glucose oxidase immobilized onto platinum nanoparticles modified graphene electrode
  • 文献类型:   Article
  • 作  者:   LIU AR, HUANG SM
  • 作者关键词:   platinum nanoparticle, glucose oxidase, graphene, biosensor
  • 出版物名称:   SCIENCE CHINAPHYSICS MECHANICS ASTRONOMY
  • ISSN:   1674-7348 EI 1869-1927
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   10
  • DOI:   10.1007/s11433-012-4782-x
  • 出版年:   2012

▎ 摘  要

The platinum nanoparticles were adsorbed on graphene oxide sheets and played an important role in catalytic reduction of graphene oxide with hydrazine, leading to the formation of graphene-Pt nanoparticles. Because of their good electronic properties, biocompatibility and high surface area, graphene-Pt based composites achieved the direct electron transfer of redox enzyme and maintained their bioactivity well. The graphene-Pt nanocomposites were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM) and selected area electron diffraction (SAED). The amperometric biosensor fabricated by depositing glucose oxidase over Nafion-solubilized graphene-Pt electrode retained its biocatalytic activity and has offered fast and sensitive glucose quantification.