• 文献标题:   Decomposition reaction kinetics of double-base propellant catalyzed with graphene oxide-copper oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   LOUAFI E, BOULKADID MK, BELGACEMI R, TOUIDJINE S, AKBI H, BELKHIRI S, BENALIOUCHE F
  • 作者关键词:   combustion catalyst, copper oxide, double base propellant, graphene oxide, kinetic, nanocomposite
  • 出版物名称:   INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
  • ISSN:   0538-8066 EI 1097-4601
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/kin.21650 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

The purpose of this paper is the investigation of the catalytic effect of graphene oxide-copper oxide nanocomposite (GCNC) on the thermal comportment and decomposition reaction kinetics of a double-base propellant (DBP) formulation. Differential scanning calorimetry (DSC) was used to conduct the thermal analysis. Using well-known iso-conversional kinetics methods, namely, Vyazovkin's nonlinear integral with compensatory effect (VYA/CE), Kissinger-Akahira-Sunose (KAS), and Flynn-Wall-Ozawa (FWO), the thermokinetic parameters for the investigated propellant, including activation energy and frequency factor, were estimated. Additionally, based on the results obtained from the kinetic analysis, the critical ignition temperature was calculated. The results showed that after the addition of GCNC, the activation energy barrier is lowered by 18%, and the critical ignition temperature is reduced.