• 文献标题:   Graphene-Based Supercapacitor with an Ultrahigh Energy Density
  • 文献类型:   Article
  • 作  者:   LIU CG, YU ZN, NEFF D, ZHAMU A, JANG BZ
  • 作者关键词:   graphene, supercapacitor, energy density, ionic liquid
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   Nanotek Instruments Inc
  • 被引频次:   1925
  • DOI:   10.1021/nl102661q
  • 出版年:   2010

▎ 摘  要

A supercapacitor with graphene based electrodes was found to exhibit a specific energy density of 85 6 Wh/kg at room temperature and 136 Wh/kg at 80 degrees C (all based on the total electrode weight) measured at a current density of 1 A/g These energy density values are comparable to that of the Ni metal hydride battery, but the supercapacitor can be charged or discharged in seconds or minutes The key to success was the ability to make full utilization of the highest intrinsic surface capacitance and specific surface area of single layer graphene by preparing curved graphene sheets that will not restack face to-face The curved morphology enables the formation of mesopores accessible to and wettable by environmentally benign ionic liquids capable of operating at a voltage >4 V