▎ 摘　　要

Chemically reduced graphene oxide possesses unique properties and leads to a secure processing method for many applications. The electrical and optical properties of graphene oxide are strongly dependent on the chemical and atomic structure. In the present work, the reduction of synthesized multilayer graphene oxide sheets by both chemical and thermal methods to use them as a substrate in the field of molecular electronic device fabrication is reported. 1-Dodecanethiol molecules are used to covalently bond on the surface atoms of reduced graphene oxide to constitute molecular electronic devices. The metal-organic molecules- reduced graphene oxide-metal junctions show a significant reduction in current levels and weak diode behavior. The observations confirm the tunneling as the conduction mechanism. The sheets are low cost, highly flexible, and can be used as a substrate to build the molecular electronic junctions.