• 文献标题:   Planar Polyolefin Nanostripes: Perhydrogenated Graphene
  • 文献类型:   Article
  • 作  者:   BOUSA D, HUBER S, SEDMIDUBSKY D, PUMERA M, SOFER Z
  • 作者关键词:   carbon nanostrip, electrocatalysi, graphane, graphene, hydrogenation
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Univ Chem Technol
  • 被引频次:   2
  • DOI:   10.1002/chem.201702691
  • 出版年:   2017

▎ 摘  要

Graphene hydrogenation gives an opportunity to introduce a band gap into the graphene electronic structure. Complete hydrogenation may lead to the graphane, a fully hydrogenated counterpart of graphene. However, pure graphane has not been successfully prepared to this day. Here, we show that hydrogenation of single-walled carbon nanotubes by means of Birch reduction leads to graphene-based carbon nanostripes with uniform dimensions. Such a material exhibits interesting electrocatalytic and magnetic properties as well huge potential for hydrogen storage since the weight concentration of hydrogen is 8.78wt.% corresponding to the composition of C1H1.22O0.05 and thus exceeding the theoretical concentration in pure graphane (7.74 wt.%). The obtained concentration of hydrogen is the highest value ever reported for any graphene-based material and significantly exceeds the ultimate goal of the U.S. Department of Energy for a hydrogen storage material of 7.5wt.%.