• 文献标题:   Diethylenetriamine functionalized graphene oxide as a novel corrosion inhibitor for mild steel in hydrochloric acid solutions
  • 文献类型:   Article
  • 作  者:   BAIG N, CHAUHAN DS, SALEH TA, QURAISHI MA
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   King Fahd Univ Petr Minerals
  • 被引频次:   26
  • DOI:   10.1039/c8nj04771e
  • 出版年:   2019

▎ 摘  要

In the present work diethylenetriamine functionalized graphene oxide (DETA-GO) has been synthesized and its corrosion inhibition performance was evaluated in 1 M HCl for mild steel. The chemical structure of the synthesized DETA-GO was analyzed by FTIR and the morphology was studied using SEM, TEM, and FTIR. The corrosion inhibition behavior was studied using weight loss studies, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. DETA-GO behaved as an efficient corrosion inhibitor as evident from the results of the electrochemical analysis. Electrochemical studies showed that the inhibition efficiency of DETA-GO increased with the concentration and reached 92.67% at a concentration of 25 mg L-1. The inhibitor exhibits a mixed type nature with cathodic predominance. The protective film of the inhibitor over the mild steel surface was examined by SEM and FTIR-ATR studies. A computational study using DFT further supports the promising corrosion inhibition behavior of DETA-GO.