• 文献标题:   Highly Sensitive Electrochemical Dopamine Sensor from Poly(diallyldimethylammonium chloride)-Functionalized Graphene Nanoribbon/Gold Nanoparticle Nanocomposite
  • 文献类型:   Article
  • 作  者:   LIU XP, TONG J, YUAN Z, YANG Y, MAO CJ, NIU HL, JIN BK, ZHANG SY
  • 作者关键词:   electrochemical, gonrs/pdda/aunps nanocomposite, biosensor
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Anhui Univ
  • 被引频次:   7
  • DOI:   10.1166/jnn.2016.10738
  • 出版年:   2016

▎ 摘  要

A novel graphene oxide nanoribbon/poly(diallyldimethylammonium chloride)/gold nanoparticle (GONR/PDDA/AuNP) nanocomposite was synthesized successfully and used for the sensitive detection of dopamine. The GONR/PDDA/AuNP nanocomposite was characterized by transmission and scanning electron microscopy. The electrochemical sensor based on GONR/PDDA/AuNP nanocomposite was studied by cyclic voltammetry and electrochemical impedance spectroscopy. Experimental parameters such as GONR/PDDA concentration, volume ratio of GONR/PDDA to AuNP, scan rates, and pH were studied to investigate their effect on peak currents. Under optimal conditions, the GONR/PDDA/AuNP-based sensor exhibited excellent electrocatalytic activity for the detection of dopamine with a wide linear range from 9.99x10(-8) to 8.69x10(-4) M and a low detection limit of 3.33x10(-8) M. Moreover, the proposed sensor exhibits high sensitivity, good reproducibility, and stability, and could therefore potentially be applied in other bioanalytical systems.