• 文献标题:   Low platinum loading PtNPs/graphene composite catalyst with high electrocatalytic activity for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   LI PJ, CHEN K, CHEN YF, WANG ZG, HAO X, LIU JB, HE JR, ZHANG WL
  • 作者关键词:   graphene, pt nanoparticle, counter electrode, dyesensitized solar cell
  • 出版物名称:   CHINESE PHYSICS B
  • ISSN:   1674-1056
  • 通讯作者地址:   Univ Elect Sci Technol China
  • 被引频次:   13
  • DOI:   10.1088/1674-1056/21/11/118101
  • 出版年:   2012

▎ 摘  要

Platinum nanoparticles (PtNPs)/graphene composite materials are synthesized by a controlled chemical reduction of H2PtCl6 on graphene sheets. The electrocatalytic activity of a PtNPs/graphene composite counter electrode for a dye-sensitized solar cell (DSSC) is investigated. The results demonstrate that the PtNPs/graphene composite has high electrocatalytic activity for the dye-sensitized solar cell. The cell employing PtNPs (1.6 wt%)/graphene counter electrode reaches an conversion efficiency (eta) of 3.89% upon the excitation of 100 mW/cm(2) AM 1.5 white light, which is comparable to that of the cell with a Pt-film counter electrode (eta = 3.76%). It suggests that one can use only 14% Pt content of the conventional Pt-film counter electrode to obtain a comparable conversion efficiency. It may be possible to obtain a high performance DSSC using the PtNPs/graphene composite with a very low Pt content as a counter electrode due to its simplicity, low cost, and large scalability.