▎ 摘 要
Platinum nanoparticles (PtNPs)/graphene composite materials are synthesized by a controlled chemical reduction of H2PtCl6 on graphene sheets. The electrocatalytic activity of a PtNPs/graphene composite counter electrode for a dye-sensitized solar cell (DSSC) is investigated. The results demonstrate that the PtNPs/graphene composite has high electrocatalytic activity for the dye-sensitized solar cell. The cell employing PtNPs (1.6 wt%)/graphene counter electrode reaches an conversion efficiency (eta) of 3.89% upon the excitation of 100 mW/cm(2) AM 1.5 white light, which is comparable to that of the cell with a Pt-film counter electrode (eta = 3.76%). It suggests that one can use only 14% Pt content of the conventional Pt-film counter electrode to obtain a comparable conversion efficiency. It may be possible to obtain a high performance DSSC using the PtNPs/graphene composite with a very low Pt content as a counter electrode due to its simplicity, low cost, and large scalability.