• 文献标题:   Heterogeneous Transition-Metal-Free Alcohol Oxidation by Graphene Oxide Supported Iodoxybenzoic Acid in Water
  • 文献类型:   Article
  • 作  者:   KIM YH, JANG HS, KIM YO, AHN SD, YEO S, LEE SM, LEE YS
  • 作者关键词:   graphene oxide, iodoxybenzoic acid, alcohol oxidation, waterbased system
  • 出版物名称:   SYNLETT
  • ISSN:   0936-5214 EI 1437-2096
  • 通讯作者地址:   Kangwon Natl Univ
  • 被引频次:   3
  • DOI:   10.1055/s-0033-1339673
  • 出版年:   2013

▎ 摘  要

The metal-free oxidation of organic compounds is one of the most demanding reactions in chemical industries. As such, iodoxybenzoic acid (IBX) is an attractive reagent due to its metal-free oxidative activity. To apply IBX for the alcohol oxidation in water, IBX was immobilized on graphene oxide (GO). GO-supported IBX reagent exhibited excellent performance for alcohol oxidation reaction in water with greater than 90% selectivity. It could be reused without significant loss of oxidative activity.