• 文献标题:   Synthesis and characterization of ZnO decorated reduced graphene oxide (ZnO-rGO) and evaluation of its photocatalytic activity toward photodegradation of methylene blue
  • 文献类型:   Article
  • 作  者:   NISAR A, SAEED M, MUNEER M, USMAN M, KHAN I
  • 作者关键词:   graphene, zno, znographene, methylene blue, photodegradation
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:  
  • 被引频次:   21
  • DOI:   10.1007/s11356-021-13520-6 EA MAR 2021
  • 出版年:   2022

▎ 摘  要

Photocatalytic treatment is one of the techniques used for the treatment of dyes-contaminated wastewater. It is important to develop an effective visible-light-driven catalyst for the treatment of dyes-contaminated wastewater. This study reports the synthesis of ZnO-reduced graphene oxide catalyst for the degradation of methylene blue. Graphene oxide was prepared by Hammer and Offeman process, while ZnO-rGO (1:1) was prepared by the chemical reduction method. The prepared ZnO-rGO composite was characterized by XRD, TEM, SEM, UV-Vis, DRS, N-2 adsorption-desorption, FTIR, and XPS analyses. The photocatalytic activity was evaluated by photodegradation of methylene blue solution under irradiation. It was found that ZnO-rGO is capable of removing the dye from water and achieved the highest dye degradation efficiency of similar to 99% within 60 min. Furthermore, the ZnO-rGO was recycled in degradation experiments without any loss in its catalytic performance. The reaction kinetics was described in terms of the Langmuir-Hinshelwood mechanism, one of the kinetics mechanisms of surface catalyzed reaction. 36.2 and 13.1 kJ/mol were calculated as the apparent and true activation energy for photodegradation of methylene blue respectively.