• 文献标题:   Highly dispersive hollow PdAg alloy nanoparticles modified ionic liquid functionalized graphene nanoribbons for electrochemical sensing of nifedipine
  • 文献类型:   Article
  • 作  者:   SHANG L, ZHAO FQ, ZENG BZ
  • 作者关键词:   graphene nanoribbon, ionic liquid, hollow pdag nanoparticle, electrochemical sensor, nifedipine
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   27
  • DOI:   10.1016/j.electacta.2015.04.024
  • 出版年:   2015

▎ 摘  要

In this paper, ionic liquid functionalized graphene nanoribbons were prepared by using 1-(3-aminopropyl)-3-methylimidazolium bromide as reducing and functionalizing reagent. Then hollow PdAg alloy nanoparticles were assembled on the composite through electrostatic interaction. The resultant hybrid material showed excellent electrocatalysis to nifedipine and thus it was used for constructing an electrochemical sensor for nifedipine. Result showed that the peak current of nifedipine was linear to its concentration in the range of 10 to 4000 nM with a detection limit of 4 nM (S/N = 3). The sensor possessed desirable reproducibility, stability and selectivity. It was successfully applied to the determination of nifedipine in real samples, and the recovery was 97.6%-101%. (C) 2015 Elsevier Ltd. All rights reserved.