▎ 摘　　要

Use of catalytic materials is regarded as the most desirable strategy to cope with sluggish kinetics of lithium polysulfides (LiPSs) transformation and severe shuttle effect in lithium-sulfur batteries (LSBs). Single-atom catalysts (SACs) with 100 % atom-utilization are advantagous in serving as anchoring and electrocatalytic centers for LiPSs. Herein, a novel kind of tungsten (W) SAC immobilized on nitrogen-doped graphene (W/NG) with a unique W-O2N2-C coordination configuration and a high W loading of 8.6 wt % is proposed by a self-template and self-reduction strategy. The local coordination environment of W atom endows the W/NG with elevated LiPSs adsorption ability and catalytic activity. LSBs equipped with W/NG modified separator manifest greatly improved electrochemical performances with high cycling stability over 1000 cycles and ultrahigh rate capability. It indicates high areal capacity of 6.24 mAh cm(-2) with robust cycling life at a high sulfur mass loading of 8.3 mg cm(-2).