• 文献标题:   Promising graphene/carbon nanotube foam@pi-conjugated polymer self-supporting composite cathodes for high-performance rechargeable lithium batteries
  • 文献类型:   Article
  • 作  者:   SUN MQ, LI H, WANG J, WANG GC
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   E China Univ Sci Technol
  • 被引频次:   21
  • DOI:   10.1016/j.carbon.2015.07.054
  • 出版年:   2015

▎ 摘  要

Three-dimensional (3D) graphene foam materials are highly favored due to large accessible surface and excellent conductive network, which can be commendably applied as self-supporting electrodes for advanced rechargeable lithium batteries (RLBs). Here, promising graphene nanosheets/acid-treated multi-walled carbon nanotubes (GNS/aMWCNT)-supported 1,5-diaminoanthraquinone (DAA) organic foams [oGCTF(DAA)] are prepared by organic solvent displacement method followed by solvothermal reaction. And then electrochemical polymerization is carried out to obtain 3D porous GNS/aMWCNT organic foam-supported poly(1,5-diaminoanthraquinone) (oGCTF@PDAA) nanocomposites, which achieves the ordered growth of homogeneous PDAA nanoparticles on GNS/aMWCNT surface due to the role of oGCTF(DAA). Such structure largely improves PDAA utilization, facilitates charge transportation and suppresses the dissolution of PDAA. As a result, the oGCTF@PDAA cathode for RLBs delivers a high discharge capacity of 289 mAh g(-1) at 30 mA g(-1) and still retains 122 mAh g(-1) at extreme 10 A g(-1) for rapid charging/discharging. Moreover, superior cycling stability is achieved with only 14.8% capacity loss after 2000 cycles even at a high current density of 1 A g(-1). (C) 2015 Elsevier Ltd. All rights reserved.