▎ 摘　　要

The amazing properties of graphene are triggering extensive interests of both scientists and engineers whereas how to fully utilize the unique attributes of graphene to construct novel graphene based composites with tailor made integrated functions remains to be a challenge. Here we report a facile approach to multi functional iron oxide nanoparticles attached graphene nanosheets (graphene @ Fe3O4) which show the integrated properties of strong supraparamagnetism electrical conductivity highly chemical reactivity, good solubility and excellent processability. The synthesis method is efficient, scalable, green, and controllable and has the feature of reduction of graphene oxide and formation of Fe3O4 nanoparticles in one step. When the feed rations are adjusted, the average diameter of Fe3O4 nanoparticles (1.2-6.3 nm), the coverage density of Fe3O4 nanoparticles on graphene nanosheets (5.3-57.9%) and the saturated magnetization of graphene @ Fe3O4 (0.5 = 44.1 emu/g) can be controlled readily. Because of the good solubility of the as prepared graphene @ Fe3O4 highly flexible and multifunctional films composed of polyurethane and a high content of graphene @ Fe3O4 (upto 60 wt.%) were fabricated by the solution processing technique. The graphene @ Fe3O4 hybrid sheets showed electrical conductivity of 0.7 S/m and can be aligned into a layered stacking pattern in an external magnetic field. The versatile graphene @ Fe3O4 nanosheets hold great promise in a wide range of fields, including magnetic resonance imaging electromagnetic interference shield microwave absorbing and so forth.