▎ 摘　　要

The application of lithium ion batteries in high power applications such as hybrid electric vehicles and electric grid systems critically requires drastic improvement in the electronic conductivity using effective materials design and strategies. Here, we demonstrate that the growth of a multi-component structure of composition LiTi2(PO4)(3) [LTP] on a reduced graphene oxide (rGO) surface via a facile synthetic strategy could achieve an ultrahigh rate capability with the total carbon content as low as 1.79 wt%. The rGO-LTP hybrid material has been prepared using a two-step approach, where the growth of TiO2 nanoparticles on the graphene oxide surface is followed by the high temperature growth of LTP on graphene sheets and simultaneous thermal reduction of graphene oxide. The LTP particles are densely packed within the ripples of rGO and form a compact, well-connected graphene network requiring no additional conductive carbon to facilitate fast electron transport from active materials to the current collector. Here, graphene not only acts as a stable conductive substrate but also helps to control the size of the formed particles. The rGO-LTP hybrid as a cathode in lithium ion batteries achieves an ultrahigh specific power of 10 000 W kg(-1) at a specific energy of 210 W h kg(-1), which corresponds to a charge and discharge time of 36 s and also retains 92% of the initial capacity after 100 cycles at a 10 C charge-discharge rate. Such an excellent performance is attributed to the multifunctional roles performed by rGO such as controlling the particle size, enhancing the electronic conductivity through a highly conductive network and rendering stability during cycling. This provides an effective design strategy for growing complex hybrid materials on graphene and engineering graphene nanosheets for advanced energy storage applications.